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Vor 9 Stunden · macroscopic quantum systems,New Journal of Physics 14, 043020 (2012). [22]A. J. Short and T. C. Farrelly, Quantum equilibration in finite time,New Journal of Physics14, 013063 (2012). [23]C. Gogolin and J. Eisert, Equilibration, thermalisation, and the emergence of statistical mechanics in closed quantum systems,Reports on Progress in Physics 79,
Vor 9 Stunden · Strictly speaking, a transition state is a thermodynamic concept, a member of an ensemble, which is in a kind of equilibrium with the reactants in Eyring’s Footnote 1 transition-state theory . Since equilibrium constants are determined by free energy differences, the transition state species is logically a free energy maximum along the reaction coordinate, in so far as a single species can ...
