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28. Juli 2022 · An experimental proof of the Lewis acidity is provided by the reaction of solvent-adducts of Al(OTeF 5) 3 with [PPh 4][SbF 6] and OPEt 3, respectively. Furthermore, their reactivity towards chloride and pentafluoroorthotellurate salts as well as (CH 3 ) 3 SiCl and (CH 3 ) 3 SiF is shown.
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- 28 July 2022
Kurt F. Hoffmann, Anja Wiesner, Simon Steinhauer, Sebastian Riedel – 2022. Title. Insights on the Lewis Superacid Al (OTeF5)3: Solvent Adducts, Characterization and Properties. Author. Kurt F. Hoffmann, Anja Wiesner, Simon Steinhauer, Sebastian Riedel. Date. 2022. Source (s) Chem. Eur. J. Appeared in. Chem. Eur. J. 2022 DOI 10.1002/chem.202201958.
28. Juli 2022 · Insights on the Lewis Superacid Al (OTeF5)3: Solvent Adducts, Characterization and Properties** - Hoffmann - 2022 - Chemistry – A European Journal - Wiley Online Library. Chemistry – A European Journal. Volume 28, Issue 57 e202201958. Research Article. Open Access.
Kurt F. Hoffmann, Anja Wiesner, Simon Steinhauer and Sebastian Riedel – 2022 Title "Insights on the Lewis Superacid Al(OTeF<sub>5</sub>)<sub>3</sub>: Solvent Adducts, Characterization and Properties"
13. Apr. 2022 · PDF | The improved preparation of the Lewis superacid Al(OTeF5)3 and several solvent adducts is presented. These range from thermally stable adducts to... | Find, read and cite all the...
Abstract Preparation and characterization of the dimeric Lewis superacid [Al(OTeF5)3]2 and various solvent adducts is presented. The latter range from thermally stable adducts to highly reactive, weakly bound species. DFT calculations on the ligand affinity of these Lewis acids were performed in order to rank their remaining Lewis acidity. An ...
Kurt F Hoffmann 1 , Anja Wiesner 1 , Simon Steinhauer 1 , Sebastian Riedel 1. Affiliation. The dimeric Lewis superacid [Al (OTeF5)3]2 and its solvent adducts are ready to test their strength in terms of fluoride ion affinity.
