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28. Juli 2021 · Statistical thermodynamics - Wikiversity. Contents. 1 Three iconic equations in thermodynamics. 2 Thermodynamic (Clausius) definition of entropy. 2.1 State variables: Pressure (P), Energy (E), Volume (V), and Temperature (T): 2.2 Heat, work and the heat engine. 2.3 Why heat and work are not state variables. 3 Carnot's Theorem.
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Entropy is a thermodynamic property just like pressure, volume, or temperature. Therefore, it connects the microscopic and the macroscopic world view. Boltzmann's principle is regarded as the foundation of statistical mechanics .
Thermodynamics — Introduction to Statistical Mechanics. 5. Thermodynamics ¶. Statistical mechanics grew out of an earlier field called thermodynamics, which was concerned with the thermal properties of liquids and gasses. It grew up around it, and then subsumed it.
Statistical thermodynamics provides the link between the microscopic (i.e., molecular) properties of matter and its macroscopic (i.e., bulk) properties. It provides a means of calculating thermodynamic properties from the statistical relationship between temperature and energy.
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Statistical thermodynamics. The primary goal of statistical thermodynamics (also known as equilibrium statistical mechanics) is to derive the classical thermodynamics of materials in terms of the properties of their constituent particles and the interactions between them.
Statistical thermodynamics is a theory that uses molecular properties to predict the behavior of macroscopic quantities of compounds. While the origins of statistical thermodynamics predate the …
This textbook provides a highly pedagogical and very thorough introduction to statistical thermodynamics suitable for a main course on thermodynamics. It also contains many problems and a large number of solved examples. It derives all the important formulae meticulously.